Looking-Glass Milk

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Looking Glass Creamery Green River Blue

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For additional information, see the Global Shipping Program terms and conditions - opens in a new window or tab This amount includes applicable customs duties, taxes, brokerage and other fees. For a superb non-technical introduction to the maths and physics involved watch this lecture by the great Richard Feynman. Unfortunately the Feynman video I linked to in this post is no longer available due to copyright issues.

Sadly, although the transcripts are published, there currently seems to be no way of watching or buying these videos anywhere. Looking-Glass milk, carvone, tartaric acid, and Jimmy Carter, to name a […]. Wonderful work!

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    • We are linking to this great content on our website. Keep up the great writing. Hello, always i used to check weblog posts here in the early hours in the dawn, for the reason that i enjoy to gain knowledge of more and more. Want more? Modern methods for enantiomer analysis are chromatography and capillary electrophoresis.


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      Here, the interaction is between the analytes and a chiral selector, which is also a chiral compound. To illustrate the procedure the three-point interaction model Fig. Only one enantiomer can have three interactions with the selector; due to the spatial arrangement, the other enantiomer can only have two interactions. It is readily apparent that the complexes differ in their stability, so that ultimately there is a separation of the enantiomers.


      The left enantiomer can ideally form 3 interactions with the chiral selector, the right enantiomer only 2. In chromatography, the chiral selector is bound to a stationary phase, in capillary electrophoresis it is added to the background electrolyte; this is called a pseudo-stationary phase, since the selector is mobile. The principle of chiral recognition of enantiomers in capillary electrophoresis and chromatography is the same, even if the transport of substances to the detector proceeds in a different manner, by using pressure in chromatography or using electrokinetic phenomena in capillary electrophoresis.

      Important chiral selectors used in capillary electrophoresis are cyclodextrins, macrocyclic antibiotics such as vancomycin or teicoplanin, chiral crown ethers, metal complexes, proteins or chiral micelles. Due to their availability, cyclodextrins are the most commonly used chiral selectors. These are cyclic oligosaccharides derived from the microbiological degradation of starch. They are shaped like a torus with a lipophilic cavity and a hydrophilic exterior surface.

      The interaction with analytes occurs via formation of inclusion complexes due to hydrophobic interactions in the lipophilic cavity or by interaction with the OH groups. By derivatisation of the primary and secondary hydroxy groups, numerous substituted cyclodextrins with modified complexation characteristics can be produced, which can be used in numerous separation modes.

      Besides applications in the chemical industry, in food or environmental samples, enantiomers play a particularly important role in pharmaceutical analysis.

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      One reason is the different effects of enantiomers of chiral drugs already mentioned. This has been demonstrated for many drugs see the example of the antimalarial drug chloroquine in Fig. Another important direction of work is the study of the enantioselective metabolism of drugs by the human body. Since the metabolising enzymes are also chiral, a particular metabolite frequently arises preferentially from one enantiomer, while the other enantiomer can be converted to a different metabolite. In addition, people differ in the activity of the metabolizing enzymes, so that drug effects and side effects can also be a consequence of stereoselective metabolism.

      As a method that requires only small sample volumes, here capillary electrophoresis also makes important contributions. Some 30 years after its introduction, capillary electrophoresis has developed into a mature, flexible analysis method that is ideally suited to enantiomer analysis and is established in many areas.


      For the miniaturised procedure only small amounts of sample and chemicals are needed, organic solvents are hardly used. Capillary electrophoresis is therefore a cost-saving and environmentally friendly method of analysis. Request information. Motion pictures from living cells. In order to observe cells at work, researchers have to bypass a physical law. One of the fastest techniques to overcome the resolution limit of classical light microscopy is high-resolution structured illumination microscopy. It makes visible details that are about a hundred nanometres in s Fungus produces highly effective surfactant.

      Mortierella alpina lives in the soil and likes to keep cool.

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